5-BROMO-2-METHYLBENZOTHIAZOLE

  • Name: 5-BROMO-2-METHYLBENZOTHIAZOLE
  • CAS: 63837-11-6
  • Purity: 99%
Inquiry

Details

Perfect Factory Offer Excellent quality 5-BROMO-2-METHYLBENZOTHIAZOLE 63837-11-6 with Safe Shipping

  • Molecular Formula: C8H6BrNS
  • Molecular Weight: 228.112
  • Vapor Pressure: 0.00217mmHg at 25°C 
  • Melting Point: 79°C 
  • Refractive Index: 1.691 
  • Boiling Point: 299.1 °C at 760 mmHg 
  • PKA: 1.14±0.10(Predicted) 
  • Flash Point: 134.7 °C 
  • PSA： 41.13000 
  • Density: 1.644 g/cm3 
  • LogP: 3.36720 

5-BROMO-2-METHYLBENZOTHIAZOLE(Cas 63837-11-6) Usage

InChI:InChI=1/C8H6BrNS/c1-5-10-7-4-6(9)2-3-8(7)11-5/h2-4H,1H3

63837-11-6 Relevant articles

Di- tert-butyl Peroxide-Mediated Radical C(sp2/sp3)-S Bond Cleavage and Group-Transfer Cyclization

Luo, Kai,Yang, Wen-Chao,Wei, Kai,Liu, Yue,Wang, Jun-Ke,Wu, Lei

, p. 7851 - 7856 (2019/10/11)

A novel strategy of cascade radical C(sp...

Ruthenium-catalyzed transformation of aryl and alkenyl triflates to halides

Imazaki, Yusuke,Shirakawa, Eiji,Ueno, Ryota,Hayashi, Tamio

supporting information, p. 14760 - 14763 (2012/11/07)

Aryl triflates were transformed to aryl ...

An improved palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides

Pan, Jun,Wang, Xinyan,Zhang, Yong,Buchwald, Stephen L.

supporting information; experimental part, p. 4974 - 4976 (2011/11/06)

A facile Pd-catalyzed conversion of aryl...

Regioselective one-pot synthesis of 2-aryl-6-bromobenzothiazole from arylaldehyde and 2-aminothiophenol with phenyltrimethylammonium tribromide in the presence of a catalytic amount of antimony(III) bromide

Sayama, Shinsei

experimental part, p. 1267 - 1274 (2011/06/27)

Various 2-aryl-6-bromo-1,3-benzothiazole...

63837-11-6 Process route

2-Methylbenzothiazole
120-75-2

2-Methylbenzothiazole

5-bromo-2-methylbenzothiazole
63837-11-6

5-bromo-2-methylbenzothiazole

6-bromo-2-methylbenzothiazole
5304-21-2

6-bromo-2-methylbenzothiazole

4-bromo-2-methyl-1,3-benzothiazole
112146-10-8

4-bromo-2-methyl-1,3-benzothiazole

Conditions
Conditions Yield
With pyridinium hydrobromide perbromide; In water;
2-methylbenzo[d]thiazol-5-yl trifluoromethanesulfonate
398132-82-6

2-methylbenzo[d]thiazol-5-yl trifluoromethanesulfonate

5-bromo-2-methylbenzothiazole
63837-11-6

5-bromo-2-methylbenzothiazole

Conditions
Conditions Yield
With [Cp*Ru(CH3CN)3]OTf; lithium bromide; at 100 ℃; for 24h; Inert atmosphere;
96%
With potassium fluoride; tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; potassium bromide; In 1,4-dioxane; at 130 ℃; for 16h; Inert atmosphere;
83%
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; triisobutylaluminum; butanone; potassium bromide; In toluene; at 100 ℃; for 24h; Inert atmosphere;
75%

63837-11-6 Upstream products

  • 29452-12-8
    29452-12-8

    3-bromothioacetanilide

  • 110704-51-3
    110704-51-3

    N-(2,5-dibromophenyl)ethanethioamide

  • 76209-05-7
    76209-05-7

    4,4′-dibromo-2,2′-dinitrodiphenyl disulfide

  • 108-24-7
    108-24-7

    acetic anhydride

63837-11-6 Downstream products

  • 110704-13-7
    110704-13-7

    2-(bromomethyl)-5-bromobenzothiazole

  • 71215-89-9
    71215-89-9

    2-methyl-5-phenylbenzo[d]thiazole

  • 1066-44-0
    1066-44-0

    trimethyltin bromide

  • 95-26-1
    95-26-1

    2,5-dimethylbenzothiazole

Related Products