Details
Chinese Manufacturer supply trans-2-Heptenal 18829-55-5 in stock with high standard
- Molecular Formula:C7H12O
- Molecular Weight:112.172
- Appearance/Colour:clear colorless to light yellow liquid
- Vapor Pressure:3.22mmHg at 25°C
- Melting Point:-53.35°C (estimate)
- Refractive Index:n20/D 1.450(lit.)
- Boiling Point:165.999 °C at 760 mmHg
- Flash Point:53.333 °C
- PSA:17.07000
- Density:0.831 g/cm3
- LogP:1.93170
trans-2-Heptenal(Cas 18829-55-5) Usage
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Synthesis Reference(s) |
Journal of the American Chemical Society, 108, p. 452, 1986 DOI: 10.1021/ja00263a015Tetrahedron Letters, 21, p. 3987, 1980 DOI: 10.1016/S0040-4039(00)92851-X |
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General Description |
trans-2-Heptenal is a volatile flavor constituent identified in heated butter and tomato. |
InChI:InChI=1/C7H12O/c1-3-5-6-7(8)4-2/h4H,2-3,5-6H2,1H3
18829-55-5 Relevant articles
Reactivity of 3-Nitro-5,6-Dihydro-4H-Pyran with Organoalanes: Preparation of (E)-α, β-Ethylenic Aldehydes
Menicagli, Rita,Guagnano, Vito,Malanga, Corrado
, p. 1871 - 1876 (1994)
3-Nitro-5,6-dihydro-4H-pyran reacts with...
A new stereoselective synthesis of trans-α, β- unsaturated carbonyl compounds.
Clinet, Jean-Claude,Linstrumelle, Gerard
, p. 3987 - 3990 (1980)
Allenic silylated ethers are efficient p...
Alkene-Zipper Catalyzed Selective and Remote Retro-ene Reaction of Alkenyl Cyclopropylcarbinol
Bruffaerts, Jeffrey,Vasseur, Alexandre,Marek, Ilan
, p. 1389 - 1396 (2018)
Reminiscent of biological systems, the i...
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Yamamoto,K. et al.
, p. 721 - 722 (1977)
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An efficient Pd@Pro-GO heterogeneous catalyst for the α, β-dehydrogenation of saturated aldehyde and ketones
Pan, Gao-Fei,Wang, Zhe,Chang, Yi-Yuan,Hao, Yue,Wang, Yi-Chen,Xing, Rui-Guang
supporting information, (2021/12/30)
An Efficient Pd@Pro-GO heterogeneous cat...
Synthesis of (5Z,7E)-dodecane-5,7-diene-1-alcohol as well as acetate and propionate thereof
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Paragraph 0032-0034, (2019/03/28)
The invention belongs to the technical f...
Fe3O4 Nanoparticles Anchored on Carbon Serve the Dual Role of Catalyst and Magnetically Recoverable Entity in the Aerobic Oxidation of Alcohols
Geng, Longlong,Zheng, Bin,Wang, Xiang,Zhang, Wenxiang,Wu, Shujie,Jia, Mingjun,Yan, Wenfu,Liu, Gang
, p. 805 - 811 (2016/03/05)
A composite of Fe3O4 nanoparticles ancho...
18829-55-5 Process route
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111-70-6
n-heptan1ol
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111-71-7
heptanal
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18829-55-5
(E)-2-Heptenal
-
-
111-14-8
oenanthic acid
| Conditions | Yield |
|---|---|
|
With
2,2,6,6-tetramethyl-piperidine-N-oxyl; oxygen; sodium acetate;
(neocuproine)Pd(OAc)2;
In
water; dimethyl sulfoxide;
at 80 ℃;
for 4h;
under 22502.3 Torr;
Further Variations:;
Pressures;
Temperatures;
Reagents;
Product distribution;
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-
-
111-71-7
heptanal
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-
18829-55-5
(E)-2-Heptenal
| Conditions | Yield |
|---|---|
|
With
Pd(at)Pro-GO (palladium at proline-functionalized graphene-oxide); air;
In
water; dimethyl sulfoxide;
at 40 ℃;
for 15h;
|
73% |
|
Multi-step reaction with 2 steps
1: 2.) SO2Cl2 / 1.) ether, RT, 1.5 h, 2.) CHCl3
2: aq. NaHCO3 / CHCl3 / 4 h
With
sulfuryl dichloride; sodium hydrogencarbonate;
In
chloroform;
|
|
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Multi-step reaction with 3 steps
1: NEt3 / ZnCl2 / hydroquinone / benzene
2: 85 percent / CH2Cl2 / 25 °C
3: 90 percent Chromat. / NaIO4 / methanol; H2O / 1 h / Ambient temperature
With
sodium periodate; triethylamine; hydroquinone; zinc(II) chloride;
In
methanol; dichloromethane; water; benzene;
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|
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Multi-step reaction with 2 steps
1: 1.) Br2, 2.) 36.5percent aq. HCl / 1.) Ethanol, room temp., 0.5 h, 2.) ethanol, reflux, 0.5 h
2: 90 percent Chromat. / NaIO4 / methanol; H2O / 1 h / 23 °C
With
hydrogenchloride; sodium periodate; bromine;
In
methanol; water;
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18829-55-5 Upstream products
-
83726-19-6
hept-2c-ene-1,4-diol
-
81149-92-0
(Z)-1,1-Diethoxy-2-hepten
-
20518-65-4
2-bromo-1,1-diethoxy-heptane
-
55454-22-3
(Z)-hept-2-en-1-ol
18829-55-5 Downstream products
-
5910-87-2
(E,E)-2,4-nonadienal
-
2122-10-3
hept-2t-enal-(2,4-dinitro-phenylhydrazone)
-
64235-53-6
(E)-1-phenyl-2-hepten-1-one
-
124665-00-5
(7R,5E)-7-<(benzyloxy)methoxy>-5-tetradecen-8-ol
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