trans-2-Heptenal

  • Name:trans-2-Heptenal
  • CAS:18829-55-5
  • Purity:99%
Inquiry

Details

Chinese Manufacturer supply trans-2-Heptenal 18829-55-5 in stock with high standard

  • Molecular Formula:C7H12O
  • Molecular Weight:112.172
  • Appearance/Colour:clear colorless to light yellow liquid 
  • Vapor Pressure:3.22mmHg at 25°C 
  • Melting Point:-53.35°C (estimate) 
  • Refractive Index:n20/D 1.450(lit.)  
  • Boiling Point:165.999 °C at 760 mmHg 
  • Flash Point:53.333 °C 
  • PSA:17.07000 
  • Density:0.831 g/cm3 
  • LogP:1.93170 

trans-2-Heptenal(Cas 18829-55-5) Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 108, p. 452, 1986 DOI: 10.1021/ja00263a015Tetrahedron Letters, 21, p. 3987, 1980 DOI: 10.1016/S0040-4039(00)92851-X

General Description

trans-2-Heptenal is a volatile flavor constituent identified in heated butter and tomato.

InChI:InChI=1/C7H12O/c1-3-5-6-7(8)4-2/h4H,2-3,5-6H2,1H3

18829-55-5 Relevant articles

Reactivity of 3-Nitro-5,6-Dihydro-4H-Pyran with Organoalanes: Preparation of (E)-α, β-Ethylenic Aldehydes

Menicagli, Rita,Guagnano, Vito,Malanga, Corrado

, p. 1871 - 1876 (1994)

3-Nitro-5,6-dihydro-4H-pyran reacts with...

A new stereoselective synthesis of trans-α, β- unsaturated carbonyl compounds.

Clinet, Jean-Claude,Linstrumelle, Gerard

, p. 3987 - 3990 (1980)

Allenic silylated ethers are efficient p...

Alkene-Zipper Catalyzed Selective and Remote Retro-ene Reaction of Alkenyl Cyclopropylcarbinol

Bruffaerts, Jeffrey,Vasseur, Alexandre,Marek, Ilan

, p. 1389 - 1396 (2018)

Reminiscent of biological systems, the i...

-

Yamamoto,K. et al.

, p. 721 - 722 (1977)

-

An efficient Pd@Pro-GO heterogeneous catalyst for the α, β-dehydrogenation of saturated aldehyde and ketones

Pan, Gao-Fei,Wang, Zhe,Chang, Yi-Yuan,Hao, Yue,Wang, Yi-Chen,Xing, Rui-Guang

supporting information, (2021/12/30)

An Efficient Pd@Pro-GO heterogeneous cat...

Synthesis of (5Z,7E)-dodecane-5,7-diene-1-alcohol as well as acetate and propionate thereof

-

Paragraph 0032-0034, (2019/03/28)

The invention belongs to the technical f...

Fe3O4 Nanoparticles Anchored on Carbon Serve the Dual Role of Catalyst and Magnetically Recoverable Entity in the Aerobic Oxidation of Alcohols

Geng, Longlong,Zheng, Bin,Wang, Xiang,Zhang, Wenxiang,Wu, Shujie,Jia, Mingjun,Yan, Wenfu,Liu, Gang

, p. 805 - 811 (2016/03/05)

A composite of Fe3O4 nanoparticles ancho...

18829-55-5 Process route

n-heptan1ol
111-70-6

n-heptan1ol

heptanal
111-71-7

heptanal

(E)-2-Heptenal
18829-55-5

(E)-2-Heptenal

oenanthic acid
111-14-8

oenanthic acid

Conditions
Conditions Yield
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; oxygen; sodium acetate; (neocuproine)Pd(OAc)2; In water; dimethyl sulfoxide; at 80 ℃; for 4h; under 22502.3 Torr; Further Variations:; Pressures; Temperatures; Reagents; Product distribution;
heptanal
111-71-7

heptanal

(E)-2-Heptenal
18829-55-5

(E)-2-Heptenal

Conditions
Conditions Yield
With Pd(at)Pro-GO (palladium at proline-functionalized graphene-oxide); air; In water; dimethyl sulfoxide; at 40 ℃; for 15h;
73%
Multi-step reaction with 2 steps
1: 2.) SO2Cl2 / 1.) ether, RT, 1.5 h, 2.) CHCl3
2: aq. NaHCO3 / CHCl3 / 4 h
With sulfuryl dichloride; sodium hydrogencarbonate; In chloroform;
Multi-step reaction with 3 steps
1: NEt3 / ZnCl2 / hydroquinone / benzene
2: 85 percent / CH2Cl2 / 25 °C
3: 90 percent Chromat. / NaIO4 / methanol; H2O / 1 h / Ambient temperature
With sodium periodate; triethylamine; hydroquinone; zinc(II) chloride; In methanol; dichloromethane; water; benzene;
Multi-step reaction with 2 steps
1: 1.) Br2, 2.) 36.5percent aq. HCl / 1.) Ethanol, room temp., 0.5 h, 2.) ethanol, reflux, 0.5 h
2: 90 percent Chromat. / NaIO4 / methanol; H2O / 1 h / 23 °C
With hydrogenchloride; sodium periodate; bromine; In methanol; water;

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