5-methyl-2-(p-tolyl)pyridine

  • Name: 5-methyl-2-(p-tolyl)pyridine
  • CAS: 85237-71-4
  • Purity: 99%
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  • Molecular Formula: C13H13 N
  • Molecular Weight: 183.253
  • Vapor Pressure: 0.00185mmHg at 25°C 
  • Boiling Point: 301.7°C at 760 mmHg 
  • PKA: 5.03±0.25(Predicted) 
  • Flash Point: 127.1°C 
  • PSA： 12.89000 
  • Density: 1.015g/cm3 
  • LogP: 3.36540 

5-methyl-2-(p-tolyl)pyridine(Cas 85237-71-4) Usage

General Description

5-Methyl-2-(p-tolyl)pyridine is a chemical compound that belongs to the class of organic compounds known as alkyl-phenylketones. These compounds are aromatic compounds containing a ketone substituted by one alkyl group, and a phenyl group. 5-Methyl-2-(p-tolyl)pyridine is commonly used as intermediates in chemical synthesis and can also be used as solvents or building blocks in organic chemistry. As an organically synthesized compound, it must be handled with care to prevent harmful effects, although specific safety and hazard details may vary based on its concentration and usage.

InChI:InChI=1/C13H13N/c1-10-3-6-12(7-4-10)13-8-5-11(2)9-14-13/h3-9H,1-2H3

85237-71-4 Relevant articles

Organic electrode material and preparation method and application thereof

-

Paragraph 0038-0042, (2021/01/30)

The invention relates to an organic elec...

Remarkably Efficient Iridium Catalysts for Directed C(sp2)-H and C(sp3)-H Borylation of Diverse Classes of Substrates

Chattopadhyay, Buddhadeb,Hassan, Mirja Md Mahamudul,Hoque, Md Emdadul

, p. 5022 - 5037 (2021/05/04)

Here we describe the discovery of a new ...

Direct suzuki-miyaura coupling with naphthalene-1,8-diaminato (dan)-substituted organoborons

Yoshida, Hiroto,Seki, Michinari,Kamio, Shintaro,Tanaka, Hideya,Izumi, Yuki,Li, Jialun,Osaka, Itaru,Abe, Manabu,Andoh, Hiroki,Yajima, Tomoki,Tani, Tomohiro,Tsuchimoto, Teruhisa

, p. 346 - 351 (2019/12/24)

The actually direct Suzuki-Miyaura coupl...

Nitroarenes as the Nitrogen Source in Intermolecular Palladium-Catalyzed Aryl C–H Bond Aminocarbonylation Reactions

Zhou, Fei,Wang, Duo-Sheng,Guan, Xinyu,Driver, Tom G.

supporting information, p. 4530 - 4534 (2017/04/11)

A three-component palladium-catalyzed am...

85237-71-4 Process route

2-Bromo-5-methylpyridine
3510-66-5

2-Bromo-5-methylpyridine

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-(4-methylphenyl)-5-methylpyridine
85237-71-4

2-(4-methylphenyl)-5-methylpyridine

Conditions
Conditions Yield
With potassium phosphate tribasic heptahydrate; palladium diacetate; In isopropyl alcohol; at 80 ℃; for 0.5h;
98%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In ethanol; water; toluene; for 24h; Inert atmosphere; Reflux;
96%
With [Pd(Cl)κ2-S,N-C6H4CS=N-(4-Py)(PPh3)]; potassium carbonate; In toluene; at 80 ℃; for 5h;
86%
With potassium phosphate; palladium diacetate; In water; isopropyl alcohol; for 4h; Reflux;
61%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0);
With potassium phosphate; bis(dicyclohexylamine)-palladium(II) acetate; In ethanol; at 20 ℃;
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0); In tetrahydrofuran; at 78 ℃; for 24h; Inert atmosphere;
para-bromotoluene
106-38-7

para-bromotoluene

2-(5-methylpyridin-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

2-(5-methylpyridin-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

2-(4-methylphenyl)-5-methylpyridine
85237-71-4

2-(4-methylphenyl)-5-methylpyridine

Conditions
Conditions Yield
With tetrakis(triphenylphosphine) palladium(0); potassium tert-butylate; In 1,4-dioxane; at 80 ℃; for 21h;
32%

85237-71-4 Upstream products

  • 3510-66-5
    3510-66-5

    2-Bromo-5-methylpyridine

  • 5720-05-8
    5720-05-8

    4-methylphenylboronic acid

  • 71-23-8
    71-23-8

    propan-1-ol

  • 68208-23-1
    68208-23-1

    3-amino-3-p-tolylpropan-1-ol

85237-71-4 Downstream products

  • 676339-81-4
    676339-81-4

    2-phenylpyridine-5,4’-dicarboxylic acid

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