Dichloro(1,5-cyclooctadiene)platinum(II)

  • Name: Dichloro(1,5-cyclooctadiene)platinum(II)
  • CAS: 12080-32-9
  • Purity: 99%
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1.What is the Dichloro(1,5-cyclooctadiene)platinum(II) ?

Catalyst for:Hydrogenative cyclization of allenynesStereoselective tandem hydrosilylation-Hiyama coupling reactionsAmino alkene cyclohydroaminationHydrative cyclization reactionsDirect amination of allylic alcohols under mild conditionsPotential anticancer agent

(η4-4-vinylcyclohexene)PtCl2
12145-50-5,33594-03-5

(η4-4-vinylcyclohexene)PtCl2

cyclo-octa-1,5-diene
5259-72-3,10060-40-9,111-78-4

cyclo-octa-1,5-diene

dichloro(1,5-cyclooctadiene)platinum(ll)
12080-32-9

dichloro(1,5-cyclooctadiene)platinum(ll)

4-ethenylcyclohexene
100-40-3

4-ethenylcyclohexene

Conditions
Conditions Yield
In chloroform-d1; slight excess of the diolefine was added to a CDCl3 coln. of Pt-complex, reaction was followed by (1)H NMR until equil. was reached; products were identified by their (1)H NMR spectra;
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

cyclo-octa-1,5-diene
5259-72-3,10060-40-9,111-78-4

cyclo-octa-1,5-diene

dichloro( 1,5-cyclooctadiene)platinum(ll)
12080-32-9

dichloro( 1,5-cyclooctadiene)platinum(ll)

Conditions
Conditions Yield
In water; acetic acid; at 110 ℃; for 3h;
95%
In water; acetic acid; to aq. soln. K2PtCl4 glacial acetic acid and COD were added and heated at 90°C for 30 min; soln. was concd. in vacuo, ppt. was filtered, washed with water, EtOH and Et2O and oven-dried at 100°C for 1 h; elem. anal.;
88%
With tin(ll) chloride; In propan-1-ol; water; at 20 ℃;
88%
In ethanol; water; at 100 ℃; for 1h; Inert atmosphere; Glovebox; Schlenk technique;
83%
With acetic acid; In water; at 90 ℃; for 0.5h; Darkness;
80%
In ethanol; water; at 65 ℃; for 0.5h;
80%
In ethanol; water; soln. of K2PtCl4 in water heated with stirring, soln. of 1,5-cyclooctadiene in EtOH added over 10 min, stirred and heated, cooled; ppt. collected, washed with water and Et2O, air dried; elem. anal.;
78%
With acetic acid; In water; at 90 ℃; for 24h; Darkness;
78%
In not given;
Inert atmosphere; Schlenk technique;
In ethanol; water; at 50 ℃;

2.What is the CAS number for Dichloro(1,5-cyclooctadiene)platinum(II) ?

The CAS number of Dichloro(1,5-cyclooctadiene)platinum(II) is 12080-32-9.

More information of Dichloro(1,5-cyclooctadiene)platinum(II) 12080-32-9 are:

CAS?Number

12080-32-9

Melting Point

285 °C (dec.)(lit.)

Boiling Point

153.5 °C at 760 mmHg

Flash Point

31.7 °C

Vapor Pressure

4.25mmHg at 25°C

HS CODE

28439000

PSA

0.00000

LogP

3.55730

3.What are another words for Dichloro(1,5-cyclooctadiene)platinum(II) ?

Synonyms?for?Dichloro(1,5-cyclooctadiene)platinum(II) 12080-32-9:Platinum,dichloro(1,5-cyclooctadiene)- (7CI,8CI);1,5-Cyclooctadiene, platinum complex;(1,5-Cyclooctadiene)platinum dichloride;(1,5-Cyclooctadiene)platinum(II)dichloride;1,5-Cyclooctadienedichloroplatinum;Dichloro(1,5-cyclooctadiene)platinum;NSC 239486;Dichloro((1,2,5,6-eta)-cycloocta-1,5-diene)platinum;

4.What is the molecular formula of Dichloro(1,5-cyclooctadiene)platinum(II)?

The chemical formula of ?Dichloro(1,5-cyclooctadiene)platinum(II) is?C8H12Cl2Pt which containing 8 Carbon atoms,12 Hydrogen atoms,2 Chlorine atoms and 1 Platinum atoms,and the molecular weight of??Dichloro(1,5-cyclooctadiene)platinum(II)?is 374.169.

5.What is Dichloro(1,5-cyclooctadiene)platinum(II) (12080-32-9) used for?

Dichloro(1,5-cyclooctadiene)platinum(II) is an organoplatinum compound with the chemical formula C8H12Cl2Pt. It is a white to pale yellow solid and is known for its catalytic properties in various chemical reactions.

InChI:InChI=1/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;

Relevant articles related to Dichloro(1,5-cyclooctadiene)platinum(II):

Article

Source

Platinum Cyclooctadiene Complexes with Activity against Gram-positive Bacteria

Frei, Angelo,Ramu, Soumya,Lowe, Gabrielle J.,Dinh, Hue,Semenec, Lucie,Elliott, Alysha G.,Zuegg, Johannes,Deckers, Anke,Jung, Nicole,Br?se, Stefan,Cain, Amy K.,Blaskovich, Mark A. T.

, p. 3165 - 3171 (2021)

CO, isocyanide, alkene, and alkyne insertions into platinaoxetane Pt-O bonds

Wu, Jianguo,Sharp, Paul R.

, p. 4810 - 4816 (2008)

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